howzit guys

[Carn]

Hi blaqboi and welcome. If you looking to learn about detailing then you have come to the right spot

I am not certain what exactly you mean by 'high polished rims' but I will have a stab at a few common ones :

If it is the diamond cut finish that is cleared over (similar to many deep dish wheels and the Mk V GTI) then just about any regular paint polish should help bring back some of the shine. If however they are the bare polished aluminium type then a fine metal polish (Meg's NXT) would be what I would recommend. Some of these polished lip style mags are also cleared over and as such would require some polishing with an normal clear coat type polish as already mentioned

As far as a starter kit goes I can help you out there